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Advanced Inorganic Chemistry

- Applications in Everyday Life

  • Format
  • Bog, paperback
  • Engelsk

Beskrivelse

Advanced Inorganic Chemistry: Applications in Everyday Life connects key topics on the subject with actual experiences in nature and everyday life. Differing from other foundational texts with this emphasis on applications and examples, the text uniquely begins with a focus on the shapes (geometry) dictating intermolecular forces of attractions, leading to reactivity between molecules of different shapes. From this foundation, the text explores more advanced topics, such as: Ligands and Ligand Substitution Processes with an emphasis on Square-Planar Substitution and Octahedral Substitution Reactions in Inorganic Chemistry and Transition Metal Complexes, with a particular focus on Crystal-Field and Ligand-Field Theories, Electronic States and Spectra and Organometallic, Bioinorganic Compounds, including Carboranes and Metallacarboranes and their applications in Catalysis, Medicine and Pollution Control. Throughout the book, illustrative examples bring inorganic chemistry to life. For instance, biochemists and students will be interested in how coordination chemistry between the transition metals and the ligands has a direct correlation with cyanide or carbon monoxide poisoning (strong-field Cyanide or CO ligand versus weak-field Oxygen molecule).

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Detaljer
  • SprogEngelsk
  • Sidetal276
  • Udgivelsesdato28-04-2017
  • ISBN139780128019825
  • Forlag Academic Press Inc
  • FormatPaperback
Størrelse og vægt
  • Vægt570 g
  • coffee cup img
    10 cm
    book img
    19,1 cm
    23,5 cm

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    Bonding Cisplatin Electronic structure. Enzyme inhibitors Chlorophyll Crystal field theory Dentin Ligands Ferrocene Magnetic properties Alzheimer Disease Hydrogenation Hemoglobin Group theory Carbon monoxide Bone Biomineralization Carbon Monoxide Poisoning Cobalt Heisenberg uncertainty principle Ligand field theory Magnetic susceptibility Electronegativity Apatite Click Chemistry Coordination complex Ferritin Linear Enamel Electron spin Magnetic moment Intermediate Contrast Agents Hydroformylation Homologation Hydrogenolysis Character tables Isomerism Geometric Lewis Bases Catalyst Oh Irreducible Representation Electron precise Facial 3-Biphosphoglycerate Acetic acid production from Methanol Activation parameters Activation volume Alkene complexes Anticancer platinum metallodrugs Arachno-structures Aromatic complexes Auranofin Back ? Base hydrolysis Axis of symmetry Arene complexes Benzene sandwich compounds Bonded atoms Associative mode aufbau principle Allowed transitions Atom angular momentum Bridging carbonyl Bridging Ligands Capping groups Center of inversion Cis-trans Isomerization Condensed clusters Co(III) amines Coordination compound Cartesian axes Complex ions Character of matrices Charge transfer spectra Bond angles ? ? )Crystal field stabilization energy (CFSE Bidentate Ligand Core electrons Boron cluster bonding Coordination Number Dissociative mode diamagnetic Cross-reaction Effective atomic number rule (EAN rule)IR stretching energies of neutral carbonyls )Effective atomic number (EAN) rule Eigen-Wilkins mechanism Electron Transfer Reactions Carborane clusters Electronic effects Encounter Complex Charge transfer to ligand Deoxyhemocyanin Coordination Numbers Coordination sphere Characteristics of catalysts Correlation diagram Distortion effects Electron-electron repulsion Closo-structures Ferrocifen First transition series Dissociative conjugate base mechanism Enterobactin Four coordinate compounds Complementary color Electronic spectra General stability of a complex (? Encounter principle Marcus-Hush theory Enthalpy and Entropy of activation Grubbs and Schrock catalysts ground state Group symmetry orbitals Crystal field splitting energy (? )Crystal field theory (CFT)Cyclopentadiene Cyclic phosphate Highest occupied molecular orbital Hemocyanin Corrinoids Hydrogenation catalyst types )Gouy Balance Heats of hydration (? Heme group Insertion reaction (ligand migration reactions)Monohydride complexes Divalent Ions Homogeneous Catalysts Doubly degenerate (eg Hund�s rule Jahn-Teller Distortion Interchange associative mechanism Hartree-Foch method Heteroboranes Hexadentate ligand Inner orbital complex Improper axis of rotation Interchange dissociative mechanism Interstitial atoms in clusters Electrostatic effects Lobes of maximum probability Electron deficient Lone Pairs Low-spin complex Magnetic resonance imaging (MRI)Metal-based NO sensors Main group cages International Union of Pure and Applied Chemists (IUPAC) rules IR active Linkage isomerism Metal Carbonyls Ferroquine Low-spin systems Macrocyclic ligand Many electron atom Labilizing effect La Porte selection rule Matrix representations Meridional Metallacarboranes F State systems Five coordinate compounds Lewis Diagram Forbidden transitions Molecular geometries Molar absorptivity Magnetic resonance imaging (MRI)Menkes disease Full-sandwich metallocenes Mixed clusters Half-sandwich metallocenes Hhyd Hydration energies Homogenous catalysts Inner sphere electron transfer Linear geometry )High-spin Complex Intimate mechanism Inversion through a point Isolobal relationships Kinetic effect Lowest unoccupied molecular orbital Metal to ligand charge transfer )Trivalent Ions
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