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    Pericyclic Chemistry

    Pericyclic Chemistry

    - Orbital Mechanisms and Stereochemistry

    Af
    Bog E-bog
    • Format
    • Bog, paperback
    • Engelsk

    Beskrivelse

    Pericyclic Chemistry: Orbital Mechanisms and Stereochemistry is a complete guide to the topic that is ideal for graduate students, advanced undergraduate students and researchers in organic chemistry. An introduction to molecular orbital theory and relevant stereochemical concepts is provided as background, with all four classes of pericyclic reactions discussed and illustrated with orbital picture representations. Also included are chapters on cycloadditions, the most versatile class, and electrocyclic reactions, sigmatropic rearrangements and group transfer reactions. A separate chapter on the construction of correlation diagrams is also included, emphasizing a practical, hands on approach. Author Dipak Kumar Mandal brings over 30 years of teaching experience to the topic and illuminates pericyclic chemistry with a clear and fresh perspective.

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  • Vægt450 g
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    10 cm
    book img
    15,2 cm
    22,9 cm

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    Asymmetric synthesis Extrusion Stereochemistry Diels-Alder reaction Allene Claisen rearrangement Reactivity Cycloaddition Ene reaction Pericyclic reaction Valence Tautomerism Molecular Orbital Atomic Orbital Photocyclization Stereoselectivity Regioselectivity 4-Cycloelimination [3] Sigmatropic rearrangement 3-Dipolar Cycloaddition Absolute configuration Achiral stereoaxis Aromaticity and antiaromaticity Charged system Cheletropic reaction Chiral stereoaxis Carbene cycloaddition Cycloaddition and cycloreversion Diels-Alder/retro-Diels-Alder strategy Diimide reduction Electrocyclic reaction Enantiotopic/diastereotopic face Correlation diagram Cheletropic cycloaddition Frontier orbital analysis Frontier orbital approach Cope rearrangement Frontier orbital Frontier orbital theory Cycloaddition with more than 6 electrons Hückel and Möbius systems Descriptor Hückel/Möbius system Inversion stereochemistry Ketene Mislow rearrangement Metallo-ene reaction Nazarov cyclization Neutral system Fulvene Multicomponent cycloaddition Orbital mechanism Higher order sigmatropic rearrangement Hetero-ene reaction Orbital correlation Photocycloaddition of benzene Photocycloaddition Prismane-benzene conversion Group transfer reaction Intramolecular Singlet vinyl carbene Site selectivity Selection rule Stereogenic centre Relative stereochemistry Sigmatropic carbon shift Sigmatropic Rearrangement Salem-Klopman equation State correlation Torquoselectivity Linear conjugated pi system Stereospecificity Wittig rearrangement Neutral and charged systems Orbital energy and coefficient Sigmatropic hydrogen shift Orbital Symmetry Transition metal alkylidene Periselectivity Retention stereochemistry Retro-ene reaction Stereospecificity/stereoselectivity Substituent effect Trimethylenemethane Stereochemical rule Vinylcyclopropane rearrangement Walk rearrangement Woodward-Hoffmann generalized rule
    Machine Name: SAXO081